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THE JAPAN INSTITUTE OF METALS PROCEEDINGS VOLUME 14 (REMXVI2000)
Rare-Earth Magnets and
Their Applications
Edited by
H. Kaneko
M. Homma
M. Okada
Copyright © 2000, | The Japan Institute of Metals All right reserved |
Published by | The Japan Institute of Metals Aramaki Aoba, Aoba-ku, Sendai 980-0845, Japan Tel: +81-22-223-3685, Fax: +81-22-223-6312 |
Contents
Vol. 1
Preface H. Kaneko, M. Homma and M. Okada
Karl Strnat Memorial Lecture
Y. Tawara ······· 1
A Tribute to Marlin S. WalmerF. G. Jones, C. H. Chen, M. H. Walmer, A. E. Ray and M. G. Benz ······· 5
Session 1: Rare Earth Magnets & Markets
Development of Rare Earth Iron Permanent Magnets
M. Sagawa ······· 17
The Role of China's Rare Earth in the GlobeJ. Yan and J. Xiong ······· 25
Further Development of Rare Earth Magnet Industry in ChinaY. Luo ······· 31
Session 2: Sintered Magnets I
Magnetic Hardening, Thermal Stability, and Microstructures for a New Class of Sm-TM High Temperature Magnets
M. S. Walmer, C. H. Chen, M. H. Walmer, S. Liu and E. Kuhl ······· 41
Micromagnetic and Microstructural Analysis of the Temperature Dependence of the Coercive Field of Sm2(Co, Cu, Fe, Zr)17 Permanent MagnetsD. Goll, W. Sigle, G. C. Hadjipanayis and H. Kronm üller ······· 61
Sintered Permanent Magnet Materials Based on SmCo7 PhaseS. Liu, E. Kuhl, C. H. Chen, M. H. Walmer, W. Gong and P. Liu ······· 71
Session 3: Sintered Magnets II
Rare-Earth Magnets with High Energy Products
Y. Kaneko ······· 83
High-Energy-Product (Pr-Nd-Ce)FeB Magnets Produced Directly from Mixed-Rare-Earth-Oxide Feed for MRI Medical Imaging ApplicationsM. G. Benz, J. C. Shei, C. H. Chen, M. S. Walmer and F. M. Doyle ······· 99
High Performance Sintered Nd-Fe-B Magnets Made by New RIP from SC AlloysS. Sasaki, J. Fidler and M. Sagawa ······· 109
Production of Sintered Nd-Fe-B Magnets with a Maximum Energy Density of 53 MGOeW. Rodewald, R. Blank, B. Wall, G. W. Reppel and H. D. Zilg ······· 119
Corrosion Behavior of Nd-Fe-B Sintered Magnets in the Refrigerant/Lubricant SystemR. Hamada, K. Tamura, M. Shimao and T. Minowa ······· 127
Session 4: Materials & Processing
Study of the Process of Didymium-Iron Double Alloy Calcium-Thermal Obtaining (Dd-Fe)
Y. Putilov, M. Kotsar, A. Mukchachev, M. Morozova and Y. Shestak ·······139
Implementation of a New Rare-Earth Industry in BrazilF. Beneduce, D. Rodrigues, P. F. Nogueira, F. J. G. Landgraf and S. Marques ······· 149
High Temperature Sm2(Co, Fe, Cu, Zr)17 Magnets and their Dynamic Thermal StabilityS. Liu, E. Kuhl, C. H. Chen, M. S. Walmer, M. H. Walmer and W. Gong ······· 159
Evolution of Microstructure and Microchemistry in the High Temperature Sm(Co, Fe, Cu, Zr)Z MagnetsY. Zhang, W. Tang, G. C. Hadjipanayis, D. Goll,H. Kronmüller, C. H. Chen, C. Nelson and K. Krishnan ······· 169
Effect of Composition and Heat Treatment on the Microstructure and Magnetic Properties of Sm(CobalFevCuyZrx)z MagnetsW. Tang, Y. Zhang, J. F. Liu, C. H. Chen and G. C. Hadjipanayis ······· 179
Effect of CoFeCuZr Coat on Anisotropic Thermal-Expansion of the Sm2Co17 MagnetsW. Pan, W. Li, L. Y. Cui, Z. H. Guo and S. Z. Dong ·······189
Structure and Magnetic Properties of SmCo7−xMnx AlloysM. Gjoka, O. Kalogirou, D. Niarchos and G. C. Hadjipanayis ·······195
Microstructures and Magnetic Properties of Strip Cast Sm2Co17 Sintered MagnetsK. Sakaki, K. Sato, T. Hashimoto, H. Nakamura and T. Minowa ·······205
Improvement of Manufacturing of High-Energy Permanent Magnets Didymium-Iron-BoronY. Putilov, M. Morozova, Y. Shestak, S. Ustinova and N. Yanchik ·······215
Hydrogen Vibration Milling (HVM): An Effective Route of Powder Preparation for Production of RE-Fe-B Sintered MagnetsA. Kianvash and I. R. Harris ·······223
Binary Powder Blending Technique (BPBT): An Effective Method in Production of (Nd, MM)2(Fe, Co, Ni)14B-Type Corrosion Resistant MagnetsH. R. Madaah-Hosseini, A. Kianvash, M. Seyyed-Reihaniand H. Yoozbashi-Zadeh ······· 229
Temperature Dependence of Magnetic Domain Structure in Nd-Fe-B Sintered MagnetsC. Ishizaka, H. Nishio, E. Kato and A. Fukuno ······· 237
Effect of Blending Additions on the Sintering Behaviour of NdFeB-Type MagnetsR. S. Mottram, B. E. Davies, M. G. Taylor and I. R. Harris ······· 247
Effect of Metal-Coating and Consecutive Heat Treatment on Coercivity of Thin Nd-Fe-B Sintered MagnetsK. T. Park, K. Hiraga and M. Sagawa ······· 257
The Flexural Characteristics of Nd-Fe-B Sintered MagnetsK. Mitake, N. Kataoka, S. Hashimoto and K. Yajima ······· 265
A Study of Grain Growth Kinetics in Sintered NdFeB MagnetsL. Xianglian, Z. Shouzeng and D. Qingfei ······· 275
Thermomagnetic Characteristics of Rare-Earth-Transition Metals Raw Materials Produced by Reduction-Diffusion ProcessesD. Rodrigues, M. Emura, S. R. Janasi, F. J. G. Landgraf and F. Beneduce Neto ······· 283
Relationships in the Fe-Nd/Sm/Pr-B Phase Diagrams Determined by Iron Crucible Reaction Analysis (ICRA)A. Luedtke, B. Stahl, I. R. Harrisand G. S. Schneider ······· 291
The Role of Lattice Defects on the Coercivity of Nucleation Controlled (NdFeB, SmCo5) MagnetsM. F. de Campos and F. J. G. Landgraf ······· 297
Effects of Zn Coating on the Microstructure and Magnetic Properties of Nd-Fe-B MagnetsY. Hu, M. Aindow, I. P. Jones and I. R. Harris ······· 307
Effects of Zinc Interdiffusion on the Magnetic Properties and Corrosion Resistance of NdFeB Powder ParticlesA. Walton, J. D. Speight, A. J. Williams and I. R. Harris ······· 315
Corrosion Protection of NdFeB-Based Rare-Earth Permanent MagnetsP. B. Gwan, S. J. Collocott and J. B. Dunlop ······· 325
Microstructure and Magnetic Properties of Hot Worked Nd-Fe-B MagnetsA. Bovda, V. Finkel, D. Kutniy, L. Onishenko, O. Utva and V. Bovda ······· 331
NdFeB Magnets Prepared by a High-Speed Forging Process: Microstructure and Magnetic PropertiesS. Rivoirard, P. de Rango, D. Fruchart,R. Perrier de la Bâthie and D. Chateigner ······· 337
Anisotropic and Coercive NdFeB Powder for Bonded MagnetsS. Rivoirard, J. G. Noudem, P. de Rango, D. Fruchart, S. Liesertand J. L. Soubeyroux ······· 347
Production of Anisotropic Powder from Hot Deformed RE-Fe-B-Cu AlloysV. S. J. Burns, A. J. Williams and I. R. Harris ······· 355
Ultrasonic Characterization of Deformation Related Parameters of Nano-Crystalline Nd-Fe-B MagnetsS. Prakash Narayan, J. Prasad and D. K. Hsu ······· 365
Solidification Behavior of Undercooled Nd-Fe-B-Ti-C Melts in Dependence on Cooling Parameters and CompositionR. Hermann, O. Filip, N. Mattern and L. Schultz ······· 375
The Magnetic and Microstructural Properties of DC Magnetron Sputtered Nd-Fe-B Films Processed by Post-Deposition Vacuum AnnealingM. A. Parry, I. R. Harris and P. J. Grundy ······· 385
Nd-Fe-B Thin Films of High Coercivity Prepared by Post-AnnealingK. Terazawa, L. Serrona, T. Okuda, N. Adachi, I. Sakamoto and A. Nakanishi ······· 393
Effect of Cr Underlayer on Microstructure and Magnetic Properties of Sm2Co17 Thin FilmsS. K. Chen, G. Y. Wu and T. S. Chin ······· 403
Effects of Nd Layer on the Magnetic Properties and Microstructure of Sputtered Nd-Fe-B Thin FilmsT. Shima, E. Aoyagi and H. Fujimori ······· 411
Magnetic Properties, Microstructure and Stability of NdFeB Magnets with Low Nd ContentSt. Alexandru, W. Kappel, N. Stancu, M. Codescu,I. Ivan and M. Mihaescu ······· 419
Session 5: Nanophase Magnets I
Current Status in Bonded Nd-Fe-B Magnets
V. Panchanathan ······· 431
Review of Rare Earth Nanocomposite MagnetsZ. Chen, Y. Zhang, M. Daniil, H. Okumura,G. C. Hadjipanayis and Q. Chen ······· 449
Hard Magnetic Properties of Melt-Spun (Nd, Dy)2Fe14(C, B) Ribbons with High CoercivityJ. B. Yang, A. Handstein, O. Gutfleisch, A. Kirchner,D. Eckert and K.-H. Müller ······· 465
Effect of Pre-Alloying Condition on the Bulk Amorphous Alloy Nd60Fe30Al10A. S. O'Connor, L. H. Lewis, R. W. McCallum, K. W. Dennis,M. J. Kramer, D. T. Kim Anh, N. H. Dan, N. H. Luong and N. X. Phuc ······· 475
Session 6: Nanophase Magnets II
Nanophase Pr and Nd/Pr-Based Rare Earth-Iron-Boron Alloys
H. A. Davies, J. I. Betancourt R. and C. L. Harland ······· 485
Effects of Simultaneous Cu-and-Nb-Doping on Phase Constitution and Magnetic Properties in Nd-Fe-B-Cr-Co-Based Fe3B/Nd2Fe14B-Type Nanocomposite Permanent MagnetsT. Miyoshi, H. Kanekiyo and S. Hirosawa ······· 495
Microstructure and Hard Magnetic Properties of Cu and Nb Containing Nd-Fe-B NanocompositesD. H. Ping, Y. Q. Wu, H. Kanekiyo, S. Hirosawa and K. Hono ······· 505
Microstructure of Alpha-Fe/NdFeB Type Nanocomposite MagnetsM. Yamasaki, H. Mizuguchi, M. Hamano, T. Kobayashi, K. Hono,H. Yamamoto and A. Inoue ······· 513
Session 7: Thin Films & Forged Magnets
High Performance Hard Magnetic Nanocomposite Films
J. P. Liu, Y. Liu, R. Skomski and D. J. Sellmyer ······· 523
Preparation and Properties of [NdFeB/Nb]n Multi-Layer FilmsJ. L. Tsai, T. S. Chin and H. Kronmüller ······· 537
Fabrication and Magnetic Properties of Nanophase Dispersed Nd2Fe14B/α-Fe and SmFe12/α-Fe Films with Crystallite Orientation of Hard PhasesH. Kato, M. Ishizone, T. Miyazaki, K. Koyama, H. Nojiri and M. Motokawa ······· 547
Magnetic Properties of SmCo Nano Films Grown by a Nd-YAG Pulsed Laser Ablation MethodC. J. Yang and S. W. Kim ······· 557
High Speed NdFeB Forged Magnets: Rheological Study of Hot Deformation and Related Permanent Magnets PropertiesS. Rivoirard, P. de Rango, D. Fruchart, Y. Chastel and C. L. Martin ······· 565
The Structure-Property Correlation of Hot Deformed Melt-Spun Nd-Fe-B Magnet.S. Prakash Narayan ······· 575
Vol. 2
Session 8: Bonded Magnets
Effect of Pr Substitution on the Magnetic Properties of Nd-Fe-Co-Cu-Nb-B System Exchange Spring Magnets
H. Yamamoto, S. Koumo and K. Kawamata ······· 585
The Effect of Co and Zr Substitutions on the Magnetic Properties of Nanostructured Didymium (Nd-Pr)-Fe-B AlloysJ. I. Betancourt R. and H. A. Davies ······· 595
Magnetic Properties and TEM Studies of Boron Enriched (Nd0.95La0.05)9.5-11.5Febal. Ti2B10.5 and (Nd0.95La0.05)11Febal.Ti2Co0-15B10.5 RibbonsW. C. Chang, S. H. Wang, S. J. Chang and H. W. Chang ······· 605
Magnetic Properties and Microstructure Studies of α-Fe/R2Fe14B-Type Nanocomposite Ribbons with Low Boron and High Boron ConcentrationW. C. Chang, I. A Chen, S. J. Chang and C. H. Yu ······· 613
Magnetic Hysteresis Properties and Structural Features of Nanocrystalline Nd9Fe84B7 Alloy Prepared by Melt-Spinning and Severe Plastic DeformationA. G. Popov, A. S. Ermolenko, V. S. Gaviko, N. N. Schegoleva,V. V. Stolyarov and D. V. Gynderov ······· 621
Magnetic Properties of Nd-Fe-Co-V-B System Bulk Exchange-Spring Magnets Formed by Spark Plasma Sintering MethodH. Ono, M. Shimada, A. Fujiki, H. Yamamoto, M. Sonoda and M. Tani ······· 631
High-Performance Nanocrystalline PrFeB-Based Bonded Permanent MagnetsD. Goll, I. Kleinschroth and H. Kronmüller ······· 641
Magnetic Properties of Nanocrystalline Pr5Fe77−xCrxB18 AlloysA. Barra-Barrera, R. K. Murakami and V. Villas-Boas ······· 651
Solidification of Nd-Fe-B Melts under Microgravity ConditionsS. Ozawa, J. Yoshizawa, T. Saito and T. Motegi ······· 661
Nanostructure Formation in Mechanically Milled Nd-Fe-B AlloysW. Kaszuwara, M. Leonowicz, M. Psoda, C. Harland and H. A. Davies ······· 669
Comparative Study of Precipitation-Hardened and Mechanically Alloyed Pr-Zr-Co Magnets with High CoercivityA. M. Gabay, Z. M. Chen, Y. Zhang and G. C. Hadjipanayis ······· 677
Effects of High Pressure Hot Compaction on the Formation, Microstructure and Magnetic Properties of Melt-Spun α-Fe/Re2Fe14B-type Nanocomposite MagnetsW. Zuocheng, Z. Shouzeng, Z. Maocai and Q. Yi ······· 687
Characteristics of Epoxy Resin Bonded Magnets Prepared from Recycled Nd-Fe-B Based Melt-Spun Powder.F. Yamashita, T. Terada, H. Onishi and H. Fukunaga ······· 695
Crystallization and Magnetic Properties of Nd2Fe14B/Fe3B Based Exchange Coupled Magnetic MaterialsS. Dong, X. Li, W. Li and W. Pan ······· 703
The Effect of Tungsten Addition on the Magnetic Properties and Microstructure of Nd-Fe-B MagnetsW. Kaszuwara, M. Leonowicz and J. Kozubowski ······· 711
Isotropic Sm-Zr-Fe-Co-B-N Bonded Magnets with High (BH)maxS. Sakurada, K. Nakagawa, F. Kawashima, T. Sawa, T. Arai and M. Sahashi ······· 719
Magnetic Properties and Demagnetization Process of Sm-Fe-N-Based Nanocomposite FlakesH. Fukunaga, T. Matsuo and F. Yamashita ······· 727
Magnetic Properties of Nitrided Sm-Fe Powders Prepared by Gas-Atomization, Rotating-Disk Atomization and Melt-Spinning ProcessesR. Omatsuzawa, N. Okochi, Y. Fujita, T. Nishio and T. Iriyama ······· 735
Injection Molded Anisotropic Magnet with Zinc-Treated Sm2Fe17N3 PowderT. Ishikawa, T. Iseki, K. Yokosawa, A. Kawamoto,I. Kaneko and K. Ohmori ······· 745
Multi-Stage Recombination Process for Producing HDDR Anisotropy NdFeB PowdersX. Liu, Y. F. Xiao, M. Yue, A. Sun and R. Wang ······· 751
The Production and Characterisation of Highly Anisotropic PrFeCoB-Type HDDR PowdersN. Cannesan, D. N. Brown, A. J. Williams and I. R. Harris ······· 757
Structure Changes in Sm2Fe17-based Permanent Magnet Materials Induced by HDDR ProcessZ. Liu, T. Ohsuna, K. Hiraga and M. Tobise ······· 767
TEM Study of Microstructures in Nd-Fe-B Based Alloys Produced by the Modified HDDR ProcessM. Itakura, T. Ishimi, N. Kuwano, K. Oki,R. Nakayama, K. Igarashi, K. Mori and K. Morimoto ······· 777
Development 2-Step Compression Molding for Nd-Fe-B Anisotropic Bonded MagnetsH. Mitarai, Y. Sugiura, H. Matsuoka and Y. Honkura ······· 787
The Effect of HDDR on the Structure and Magnetic Properties of Sm-Fe-Ti-B-N PowdersM. Tobise, Z. Liu, M. Shindoh, S. Tanigawa and K. Hiraga ······· 793
Ta-Doped SmFe NitridesP. J. McGuiness, K. Zu´zek, G. Dra´zic and S. Kobe ······· 803
Enhancement of Heat Resistance of Nd-Fe-B Anisotropic Magnet by Dy Addition in HDDR ProcessN. Hamada, C. Mishima, H. Mitarai and Y. Honkura ······· 813
Observation by Mössbauer Effect Spectroscopy of the Formation of t-Fe3B in Solid and Coventional Hydrogen Disproportionated Nd-Fe-B AlloyF. D. Saccone, F. H. Sánchez, C. Rodríguez Torres,B. Gebel and O. Gutfleisch ······· 821
Sm2(Fe, Ga)17Cy MagnetsM. Kubis, K.-H. Müller, A. Kirchner, L. Schultz and I. R. Harris ······· 827
Magnetic Properties and Stability of Bonded Magnets Produced from Zn Metal-Sorbed Nd-Fe-B HDDR PowdersK. Machida, K. Noguchi, M. Nishimura, M. Hamaguchi and G. Adachi ······· 835
Preparation and Characterization of Composite-Type Bonded Magnets of Sm2Fe17Nx and Nd-Fe-B HDDR PowdersK. Noguchi, K. Machida and G. Adachi ······· 845
Preferential Site Occupancy of Zr in Nd2 Fe14B Based Magnets; Effect of Concentration and HDDR ProcessM. Matsuura, A. Ashfaq, K. Konno and M. Sakurai ······· 855
Session 9: HDDR Process
Production of Anisotropic Nd-Fe-B HDDR Powder with High Coercivity
K. Igarashi, K. Mori, K. Morimoto, R. Nakayama, M. Itakura,N. Kuwano, K. Oki ······· 865
Magnetic Properties of NdFeB Anisotropic Magnet Powder Produced by the d-HDDR MethodC. Mishima, N. Hamada, H. Mitarai and Y. Honkura ······· 873
Exchange Coupled Sm2Co17 Magnets Obtained by Reactive Milling and RecombinationO. Gutfleisch, A. Bollero, D. Eckert, B. Gebel,M. Kubis, K.-H. Müller and L. Schultz ······· 883
Localisation of Zr, Nb, and Ga in Nd-Fe-B Alloys: An X-Ray Absorption Fine Structure StudyP. de Rango, F. N. Genin, D. Fruchart,A. Traverse, S. Rivoirard and I. Popa ······· 893
Session 10: Applications I
Application of Halbach Cylinders to Electrical Machines
D. Howe and Z. Q. Zhu ······· 903
The Application of RE Magnets in Electrical MachinesR. E. Hanitsch ······· 923
Session 11: Applications II
RE Bonded Magnet for High Performance Motors
F. Yamashita ······· 937
Improved Representation of the Magnetization and Resulting Field in Isotropic NdFeBP. Campbell, D. Miller, J. Simkin and Y. Zhilichev ······· 955
Analytical Design of New Linear Actuators and Loudspeaker MotorsM. Berkouk, V. Lemarquand and G. Lemarquand ······· 963
A Novel Electromagnetic Planar Actuator with Neodymium-Iron-Boron Permanent MagnetsA. F. Flores Filho, A. A. Susin and M. A. da Silveira ······· 973
Session 12: Applications III
Preparation of TbFe2 Thin Film by Ion Plating Process
Y. Matsumura, H. Uchida, M. Ono and H. Kaneko ······· 985
Recent Progress of Giant Magnetostrictive Materials in ChinaS.-Z. Zhou, X. Gao, M. Zhang and Z. Shi ······· 995
Analysis of Gap Winding Motor with Rare-Earth Permanent MagnetsT. Higuchi, J. Oyama and E. Yamada ······· 1001
Backward Extruded Ring Magnets in Rotary Electric MachinesD. Hinz, P. O'Beirne, A. Kirchner, W. Stass, O. Gutfleisch,V. Panchanathan, K.-H. Müller and L. Schultz ······· 1011
Design and Analysis of a Reciprocating Moving-Magnet Actuator Employing Bonded NdFeB MagnetsR. E. Clark, G. W. Jewell and D. Howe ······· 1021
Motor Simulation on Interior Permanent Magnet MotorK. Miyata and K. Ohashi ······· 1031
Modular Permanent Magnet Brushless Machines for Aerospace and Automotive ApplicationsK. Atallah and D. Howe ······· 1039
A Sensorless High-Speed Brushless DC MotorJ. D. Ede, Z. Q. Zhu and D. Howe ······· 1049
Spiral-Type Magnetic Micro-MachineK. Ishiyama, M. Sendoh, A. Yamazaki, K. I. Arai and M. Inoue ······· 1059
Design of Metal Mold with Closed Magnetic Circuit using Plastic-Bonded Anisotropic MagnetY. Matsuyama, H.-Y. Zhao and D.-Y. Ju ······· 1067
Optimum Design of Magnetic Circuits Using a Rosenblock MethodK. Kakuno and K. Ohashi ······· 1075
Application of Rare Earth Magnet to Magnetic Tracking System for AutomobileY. Honkura, H. Toki and M. Yamamoto ······· 1083
A Magnetic Water-Treatment Device: The Influence of Magnetic Field on the Crystallisation Form of Calcium CarbonateS. Kobe, G. Drazi´c and P. J. McGuiness ······· 1093
Clinical Observation of Rare-Earth Magnetic Acne-Remedial Beauty Mask with Chinese Medicine in Treatment for AcneC. S. Zhao and D. L. Dong ······· 1103
Development of a Thin Dental Magnetic Attachment with Capped Magnetic CircuitL. Tian, A. Watarai, K. Arai and Y. Honkura ······· 1107
Electromagnetic Wave Absorption of α-Fe Structure Produced by Disproportionation Reaction of Sm2Fe17 CompoundT. Maeda, S. Sugimoto, T. Kagotani, D. Book, M. Homma,H. Ota and Y. Houjou 1113
Magnetic Field Adjustment on Variable Polarizing Undulator (APPLE-2)H. Kobayashi, K. Kakuno, N. Hirota and K. Ohashi ·······1121
The Pulsed Field Magnetometer - a Tool for Characterizing Permanent MagnetsR. Grössinger, M. Küpferling, A. Wimmer, M. Taraba, W. Scholz,J. Dudding, P. Lethuillier, B. Enzberg-Mahlke,W. Fernengel and G. Reyne ······· 1129
Manufacturing Process and Property Analysis of Magnetic Material with Positive Magnetic Temperature CoefficientY. Matsuyama, D.-Y. Ju and H.-Y. Zhao ·······1139
Magnetic Hardening in Glass Coated MicrowiresJ. González, A. Zhukov and M. Vazquez ······· 1149
Permanent Magnet Sensor for Large Linear DisplacementJ.-P. Yonnet, M. Tur and J.-Y. Voyant ······· 1155
Analytical Modelling of Different Structures of Permanent Magnet Motors for Electric and Hybrid VehiclesA. Fonseca, C. Chillet, J.-P. Yonnet, P. Langry and A.-L. Bui-Van ······· 1163
Author Index······· 1173
Subject Index······· 1176